The merger of electro-reduction and hydrogen bonding activation for a radical Smiles rearrangement
Liyuan Lan, Kun Xu, Cheng‐Chu Zeng
Abstract
-arylpropiolamides without external radical precursors and prefunctionalization steps was accomplished. [DBU][HOAc], a readily accessible ionic liquid, was exploited for the first time both as a hydrogen bonding donor and as a supporting electrolyte.
Topics & Concepts
Smiles rearrangementReduction (mathematics)ChemistryHydrogen bondPhotochemistryHydrogenStereochemistryOrganic chemistryMoleculeMathematicsGeometryRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsPhenothiazines and Benzothiazines Synthesis and Activities