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Facile construction of a double network cross-linked luminescent supramolecular elastomer by hydrosilylation and pillar[5]arene host–guest recognition

Rong Fu, Junying Zhang, Shaojie Liu, Xing‐Dong Xu, Shengyu Feng

2020Chemical Communications27 citationsDOI

Abstract

Reticulated copolymer host pillar[5]arene cross-linked with poly(dimethylsiloxane) (PDMS) was synthesized for the facile construction of a double network cross-linked elastomer upon noncovalently cross-linking with tetraphenyethylene (TPE)-based tetratopic guests through host-guest interactions. The obtained sample strips had better mechanical properties and luminescence capabilities.

Topics & Concepts

PillarElastomerHydrosilylationLuminescenceSupramolecular chemistryCopolymerHost (biology)Materials sciencePolymer chemistryNanotechnologyMoleculeChemistryComposite materialPolymerOptoelectronicsOrganic chemistryEngineeringBiologyEcologyCatalysisStructural engineeringLuminescence and Fluorescent MaterialsSupramolecular Chemistry and ComplexesSupramolecular Self-Assembly in Materials
Facile construction of a double network cross-linked luminescent supramolecular elastomer by hydrosilylation and pillar[5]arene host–guest recognition | Litcius