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Tough and sustainable solid–solid phase change materials achieved <i>via</i> reversible crosslinking for thermal management

Fubin Luo, Yaofei Xu, D. Wang, Lebin Zhan, Yixin Feng, Bili Lin, Chunrui Zhai, Hongzhou Li

2025Materials Horizons17 citationsDOI

Abstract

. The reversible phase transition of polyethylene glycol (PEG) segments locked within the networks enables excellent smart shape memory features. Notably, the networks can undergo rearrangement through interesterification, thereby acquiring recyclability and self-healing properties. Additionally, the thermal conductivity of the matrix is enhanced through the addition of BN. It is further demonstrated that the thermally conductive PCMs retain high toughness, recyclability and shape memory features, while simultaneously exhibiting potential thermal management capabilities.

Topics & Concepts

Materials scienceThermal management of electronic devices and systemsPhase changeThermalThermal energy storagePhase (matter)NanotechnologyChemical engineeringEngineering physicsMechanical engineeringThermodynamicsChemistryEngineeringOrganic chemistryPhysicsPhase Change Materials Research
Tough and sustainable solid–solid phase change materials achieved <i>via</i> reversible crosslinking for thermal management | Litcius