μ-Oxo-bridged diiron(<scp>iii</scp>) complexes of tripodal 4N ligands as catalysts for alkane hydroxylation reaction using <i>m</i>-CPBA as an oxidant: substrate <i>vs.</i> self hydroxylation
Mani Balamurugan, Eringathodi Suresh, Mallayan Palaniandavar
Abstract
-CPBA as an oxidant. The electronic effects of ligand donors dictate the efficiency and selectivity of catalytic hydroxylation of alkanes.
Topics & Concepts
ChemistryHydroxylationIntramolecular forceCyclohexaneCatalysisAdamantaneOctahedral molecular geometryLigand (biochemistry)RedoxMedicinal chemistryChlorideProtonationPhotochemistryCrystal structureStereochemistryCrystallographyInorganic chemistryIonOrganic chemistryBiochemistryEnzymeReceptorMetal-Catalyzed Oxygenation MechanismsMagnetism in coordination complexesPorphyrin and Phthalocyanine Chemistry