Non-traditional thermal behavior of Co(<scp>ii</scp>) coordination networks showing slow magnetic relaxation
Anna Świtlicka, B. Machura, Alina Bieńko, Sandra Kozieł, Dariusz C. Bieńko, Cyril Rajnák, Roman Boča, Andrew Ozarowski, Mykhaylo Ozerov
Abstract
Three new Co( ii ) coordination polymers show the DC magnetic data consistent with the S = 3/2 spin system with large zero-field splitting D > 0, which was confirmed by HF EPR and FIRMS measurements.
Topics & Concepts
Electron paramagnetic resonanceRelaxation (psychology)Coordination polymerThermalMagnetic fieldCoordination complexMaterials scienceChemical physicsPolymerCoordination numberCondensed matter physicsSpin (aerodynamics)Nuclear magnetic resonanceCrystallographyChemistryIonPhysicsMetalThermodynamicsPsychologyMetallurgyOrganic chemistrySocial psychologyQuantum mechanicsMagnetism in coordination complexesMetal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal Complexes