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<i>In situ</i> Raman spectroscopy reveals the structure evolution and lattice oxygen reaction pathway induced by the crystalline–amorphous heterojunction for water oxidation

Jianing Dong, Zhengxin Qian, Pan Xu, Mufei Yue, Ru-Yu Zhou, Yanjie Wang, Zi‐Ang Nan, Siying Huang, Quanfeng Dong, Jian‐Feng Li, Feng Ru Fan, Zhong‐Qun Tian

2022Chemical Science76 citationsDOIOpen Access PDF

Abstract

The amorphous NiO x /crystalline α-Fe 2 O 3 heterojunctions were constructed and exhibited outstanding OER activities. Through the collaboration of multiple characterization techniques, the Lewis acid effect of Fe 3+ was revealed at molecular level.

Topics & Concepts

Raman spectroscopyAmorphous solidHeterojunctionIn situOxygenMaterials sciencePhotochemistryOxygen evolutionSpectroscopyLattice (music)ChemistryCrystallographyPhysical chemistryOptoelectronicsOpticsPhysicsOrganic chemistryElectrochemistryElectrodeAcousticsQuantum mechanicsSemiconductor materials and devicesElectrocatalysts for Energy ConversionElectronic and Structural Properties of Oxides
<i>In situ</i> Raman spectroscopy reveals the structure evolution and lattice oxygen reaction pathway induced by the crystalline–amorphous heterojunction for water oxidation | Litcius