Highly efficient recovery of vanadium from Abu Zeneima ferruginous siltstone, Southwestern Sinai, Egypt, by a novel polyimine‐based chelating ligand
Bahig M. Atia, Hend A. Radwan, Walaa A. Kassab, Hazem Sarhan, Mohamed A. Gado, Adel E.‐S. Goda
Abstract
Abstract To extract V 5+ ions from the ferruginous siltstone in the Abu Zeneima region of Southwestern Sinai, Egypt, a chelating polyimine ligand (PVAm‐Ben) was synthesized via a condensation reaction involving polyvinyl amine and α‐hydroxy ketone (Benzoin). The structure of PVAm‐Ben underwent comprehensive characterization employing various techniques, namely; FT‐IR, 1 H‐NMR, 13 C‐NMR, and GC/MS analyses. Experimental factors controlling such as pH, time, initial concentration, dosage, temperature, and stripping, were systematically optimized to enhance measurement accuracy. Under conditions of 25°C, 0.015 mol/L, and 30 minutes, PVAm‐Ben/C 2 H 4 Cl 2 exhibited remarkable retention capacity at pH 3. Linear regression analysis results suggested the release of a mole of H + during the extraction process. The stability constant (log β = 2.1882) of the PVAm‐Ben/V 5+ complex was determined, yielding a value of 154.24. The stoichiometry mechanism between PVAm‐Ben and V 5+ ions displayed a linear correlation (slope: 0.9922), signifying 1 mole of PVAm‐Ben reacting with 1 mole of vanadium. The pseudo‐second‐order kinetic model indicated an exothermic, spontaneous, and advantageous extraction process at low temperatures. Efficient stripping of PVAm‐Ben/C 2 H 4 Cl 2 loaded with vanadium was achieved using 0.05 M NaOH with a 99% efficiency rate. Ultimately, enhanced variables were employed to yield a V 2 O 5 concentrate with a vanadium content of 55% and a purity level of 98.21%.