A conjugated Schiff-base macrocycle weakens the transverse crystal field of air-stable dysprosium single-molecule magnets
Shuting Liu, Yolimar Gil, Chen Zhao, Jinjiang Wu, Zhenhua Zhu, Xiaolei Li, Daniel Aravena, Jinkui Tang
Abstract
The dominance of a self-condensed conjugated macrocycle over a [2 + 2] conventional macrocycle in weakening the transverse crystal field and boosting axiality provides a new route to construct high-performance air-stable lanthanide SMMs.
Topics & Concepts
DysprosiumConjugated systemSchiff baseMaterials scienceMagnetMoleculeTransverse planeCrystallographyLanthanideChemistryPolymer chemistryInorganic chemistryPhysicsPolymerOrganic chemistryComposite materialIonEngineeringStructural engineeringQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesAdvanced NMR Techniques and Applications