Suppressed Self‐Reduction of Manganese in Mg<sub>2</sub>SnO<sub>4</sub> via Li<sup>+</sup> Incorporation with Polychromatic Luminescence for Versatile Applications
Junpeng Xue, Tao Hu, Fuqiang Li, Feng‐Wu Liu, Hyeon Mi Noh, Bo Ram Lee, Byung Chun Choi, Sung Heum Park, Jung Hyun Jeong, Peng Du
Abstract
Abstract Herein, the self‐reduction behavior of manganese (Mn) in Mg 2 SnO 4 (MSO) host lattices prepared by using the solid‐state reaction technique in air atmosphere is reported. Excited by 282 nm, only the emission of Mn 2+ is seen, and the observed results are confirmed by theoretical calculation based on the density functional theory. Noteworthy, with the codoping of Li + , the self‐reduction process of Mn is suppressed, leading to the coexistence of Mn 2+ and Mn 4+ in MSO host lattices along with the multicolor emissions. For the suppressed self‐reduction behavior, possible hypotheses are proposed to elucidate the corresponding mechanisms. Furthermore, benefiting from the different thermal quenching behaviors of Mn 2+ and Mn 4+ , ratiometric optical thermometers with high sensitivity of 6.59% K −1 are designed. Moreover, the prepared phosphors possess a good green afterglow phenomenon, in which their trap depth are 0.71 and 0.91 eV. In addition, via using the designed phosphors, applications in anti‐counterfeiting, fingerprint identification, and optical information storage are also realized.