Functional group induced structural diversities and photocatalytic, magnetic and luminescence sensing properties of four cobalt(<scp>ii</scp>) coordination polymers based on 1,3,5-tris(2-methylimidazol-1-yl)benzene
Jun Wang, Ningning Chen, Chen Zhang, Li-Yong Jia, Liming Fan
Abstract
Based on the designed tripodal linker timb, four cobalt(<sc>ii</sc>) coordination polymers, {[Co<sub>4</sub>(timb)<sub>2</sub>(Br–IPA)<sub>4</sub>]·5H<sub>2</sub>O}<sub>n</sub> (<bold>1</bold>), {[Co(timb)<sub>0.5</sub>(NH<sub>2</sub>–IPA)]·4H<sub>2</sub>O}<sub>n</sub> (<bold>2</bold>), {[Co<sub>5</sub>(timb)<sub>4</sub>(OH–IPA)<sub>4</sub>]·2NO<sub>3</sub>·2DMA·2H<sub>2</sub>O}<sub>n</sub> (<bold>3</bold>), and {[Co<sub>3</sub>(timb)<sub>2</sub>(SO<sub>3</sub>–IPA)<sub>2</sub>(H<sub>2</sub>O)<sub>2</sub>]·8H<sub>2</sub>O}<sub>n</sub> (<bold>4</bold>), have been obtained.
Topics & Concepts
CobaltCrystallographyLuminescenceGroup 2 organometallic chemistryChemistryMaterials scienceInorganic chemistryMoleculeOptoelectronicsOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesPolyoxometalates: Synthesis and Applications