Effects of hydrogen blending ratios and CO2 on hydrogen embrittlement of X65 steel in high-pressure offshore hydrogen-blended natural gas pipelines
Dechun Cui, Yunlong Bai, Liang Xiong, Bo Yu, Boxin Wei, Chenghui Sun
Abstract
In this study, the effects of hydrogen blending ratios and high CO 2 content on hydrogen embrittlement (HE) of offshore natural gas X65 pipeline steel were investigated. In high-pressure hydrogen gas, the impact of hydrogen content on yield strength and tensile strength was minimal. However, the effect on elongation was more significant, with the area decreasing and the HE index increasing until the hydrogen-blended ratio approached 30%, at which point the HE index reached 8.94%. Introducing CO 2 into high-pressure hydrogen-rich gas further increased the HE index with high CO 2 content. At 40% CO 2 , the HE index was 2.42 times higher than in high-pressure hydrogen-blended mixtures (30% H 2 ). Additionally, the local fracture morphology transitions from ductile to quasi-cleavage fracture with the addition of CO 2 and H 2 .