Facile fabrication of polypyrrole/<scp>NiO<sub>x</sub></scp> core‐shell nanocomposites for hydrogen production from wastewater
A. Atta, Hani Negm, E. Abdeltwab, Mohamed Rabia, M. M. Abdelhamied
Abstract
Abstract This work highlights testing the polymer nanocomposite for hydrogen gas production from wastewater (sewage water). The in‐situ polymerization technique is used to prepare polypyrrole (PPy) and PPy/NiO x nanocomposite films on a glass substrate. The film's ability to generate hydrogen from sewage water is then evaluated. The XRD and XPS confirmed the formation of two types of NiO X : NiO and Ni 2 O 3 . The optical property of the composite is greater than the polymer under the insertion of NiO x as a core for the polymer coating shell, in which the band gap values are 2.25 and 1.81 eV, respectively. The TEM confirmed the PPy/NiO x core‐shell formation, in which the polymer shell (20 nm) coated the NiO X core (170 nm). The electrochemical testing for H 2 gas production is carried out through a three‐electrode cell. The effect of light on/off, wavelengths, and temperature on the H 2 production is applied. Under off/on light, the produced current density ( J ph ) value is enhanced from 5 to 16 μA, respectively. The effect of monochromatic light: 440, 540, and 730 nm are tested, and the produced J ph values are −1.28, −1.16, and −1.14 μA cm −2 , respectively. In which, the decreasing J ph value with increasing of the monochromatic light confirmed the behavior of the photoelectrode under different optical regions. The J ph values increase from −1.6 to −5.8 μA cm −2 with a rise in temperature from 30 to 55°C. Moreover, enthalpy (Δ H *), activation energy ( E a ), and entropy (Δ S *) of thermodynamic processes are determined using the photoelectrode response at different temperatures.