Click Chemistry ‐ Inspired Synthesis of Porphyrin Hybrid Glycodendrimers as Fluorescent Sensor for Cu(II) Ions
Anand K. Agrahari, Sunil Kumar, Mrituanjay D. Pandey, Sanchayita Rajkhowa, Manoj K. Jaiswal, Vinod K. Tiwari
Abstract
Abstract An expeditious and modular CuAAC ‘click’ protocol has been exploited for the construction of porphyrin cored hybrid glycodendrimers of G 1 and G 2 generation. The developed porphyrin hybrid glycodendrimers were characterized using extensive spectral analysis including NMR ( 1 H, 13 C, and 19 F), MS, MALDI‐TOF, IR, and SEC datas and evaluated for their sensing ability for a range of metal ions, where they displayed notable sensing for Cu(II) ion with solvatochromism properties.
Topics & Concepts
PorphyrinSolvatochromismClick chemistryChemistryFluorescenceMetal ions in aqueous solutionCombinatorial chemistryIonPhotochemistryOrganic chemistryMoleculePhysicsQuantum mechanicsCarbohydrate Chemistry and SynthesisPorphyrin and Phthalocyanine ChemistryMolecular Sensors and Ion Detection