Combination of S···N and S···Cl Noncovalently Conformational Locks for Constructing <scp>High‐Planarity</scp> and <scp>Low‐Cost Nonfused‐Ring</scp> Electron Acceptors<sup>†</sup>
Ziyang Han, Congqi Li, Xiaobin Gu, Xiao Han, Sixuan Wang, Yanan Wei, Jinhua Gao, Zhixiang Wei, Yunhao Cai, Xin Zhang, Hui Huang
Abstract
Comprehensive Summary By employing thiazole and 4‐chlorothiazole as the A′ units, two A‐D‐A′‐D‐A type nonfused‐ring electron acceptors (NFREAs) Tz‐H and Tz‐Cl were designed and synthesized. Replacing thiazole in Tz‐H with 4‐chlorothiazole can not only remarkably shorten the synthetic route through C—H direct arylation but also enhance molecular planarity with the simultaneous incorporation of S···N and S···Cl noncovalently conformational locks (NoCLs). The photovoltaic devices based on PM6: Tz‐Cl exhibited a power conversion efficiency as high as 11.10%, much higher than that of PM6: Tz‐H (6.41%), mainly due to more efficient exciton dissociation, better and more balanced carrier mobility, less charge recombination, and more favorable morphology. These findings demonstrate the great potential of NoCLs in achieving low‐cost and high‐performance NFREAs.