Magnetic Co-doped 1D/2D structured γ-Fe2O3/MoS2 effectively activated peroxymonosulfate for efficient abatement of bisphenol A via both radical and non-radical pathways
Junge Xu, Dong Wang, Die Hu, Ziwei Zhang, Junhong Chen, Yingmu Wang, Yifeng Zhang
Abstract
Abstract Iron-based catalysts have been widely used to treat refractory organic pollutants in wastewater. In this paper, magnetic Co- γ -Fe 2 O 3 was synthesized by a facile tartaric acid-assisted hydrothermal method, and Co- γ -Fe 2 O 3 /MoS 2 nanocomposite catalyst was obtained via in situ growth of MoS 2 nanosheets on Co- γ -Fe 2 O 3 nanoparticles. The nanocomposite catalysts were used to decompose bisphenol A (BPA) by activating peroxymonosulfate (PMS). It was shown that only 0.15 g/L catalyst and 0.5 mmol/L PMS degraded 10 mg/L of BPA (99.3% within 10 min) in the pH range of 3–9. PMS was activated due to redox cycling among the pairs Co(III)/Co(II), Fe(III)/Fe(II), and Mo(VI)/Mo(IV). Quenching experiments and electron paramagnetic resonance spectroscopy demonstrated that both radical and non-radical pathways were involved in BPA degradation, in which active radical sulfate radical and non-radical singlet oxygen were the main reactive oxygen species. Ten intermediates were identified by liquid chromatography-coupled mass spectrometry, and three possible BPA degradation pathways were proposed. The toxicity of several degradation intermediates was lower, and Co- γ -Fe 2 O 3 /MoS 2 exhibited excellent reusability and could be magnetically recovered.