Organocatalytic hydroboration of olefins in pyrrolidinium ionic liquids
Paweł Huninik, Jakub Szyling, Agnieszka Czapik, Jędrzej Walkowiak
Abstract
ILs organocatalyzed regioselective hydroboration of alkenes with HBpin provides anti-Markovnikov adducts with high yields and selectivity. The system allows catalyst recycling up to 30 runs. Transformations of alkylboronic esters are also included.
Topics & Concepts
HydroborationChemistryRegioselectivitySelectivityCatalysisIonic liquidOrganic chemistryMarkovnikov's ruleAdductOrganocatalysisEnantioselective synthesisOrganoboron and organosilicon chemistryAsymmetric Synthesis and CatalysisChemical Synthesis and Reactions