Symbiotically Reinforced Bimetallic Photocatalysis in Conjugated Metal−Organic Framework Nanosheets
Jianming Li, Qia‐Chun Lin, Ning Li, Zhihua Li, Guiping Tan, Shou‐Jie Liu, Lai‐Hon Chung, Wei‐Ming Liao, Lin Yu, Jun He
Abstract
Abstract Compared to monometallic counterparts, bimetallic two‐dimensional conjugated metal‐organic framework (2D c‐MOF) nanosheets possess preferable metal tunability and synergistic effect for performance optimization, yet rarely developed in photocatalytic hydrogen evolution to date. In this study, a feasible post‐synthetic strategy of second metal installation (SMI) is proposed and applied to construct a crystalline bimetallic 2D c‐MOF nanosheet, HTHATN‐Ni‐Pt‐NS. HTHATN‐Ni‐Pt‐NS exhibits high electrical conductivity and efficient hydrogen evolution with the rate of 47.2 mmol g −1 h −1 , which is 13.5‐fold higher than that of pristine HTHATN‐Ni‐NS without Pt II decoration under visible light irradiation. Experimental and theoretical analysis reveal that introduction of low amount of Pt II provides catalytically active metal sites and optimizes the Δ G H * value of Ni II centers, thus resulting in the enhanced performance of proton reduction. This study represents the first example of symbiotic bimetallic centers in MOF nanosheets highlighting SMI strategy as an efficient approach to construct photocatalysts.