A microporous Ce-based MOF with the octahedron cage for highly selective adsorption towards xenon over krypton
Xiaoling Wu, Zi‐Jian Li, Zhou He, Lin Li, Zhenghua Qian, Nan Qian, Xinxin Chu, Wei Liu
Abstract
) at 293 K (1 bar) with a Henry's selectivity of 8.24 (Xe/Kr), and an ideal adsorbed solution theory selectivity of 14.9 (Xe : Kr 20 : 80). The result of the dynamic breakthrough experiment also indicates a good separation for Xe/Kr with Ar.
Topics & Concepts
Microporous materialKryptonXenonSelectivityAdsorptionNoble gasBar (unit)ChemistryOctahedronSelective adsorptionNuclideAnalytical Chemistry (journal)RadiochemistryPhysical chemistryCrystallographyOrganic chemistryCrystal structureCatalysisPhysicsNuclear physicsMeteorologyMetal-Organic Frameworks: Synthesis and ApplicationsGas Sensing Nanomaterials and SensorsCatalytic Processes in Materials Science