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Flexible Self-Powered Weak Light Detectors Based on ZnO/CsPbBr<sub>3</sub>/γ-CuI Heterojunctions

Ruofei Xing, Peng Shi, Dong Wang, Zhenfa Wu, Yufeng Ge, Yuzhi Xing, Lin Wei, Shishen Yan, Yufeng Tian, Lihui Bai, Yanxue Chen

2022ACS Applied Materials & Interfaces14 citationsDOI

Abstract

Halide perovskites (HPs) with marvelous optical and electrical properties are regarded as one of the competitive candidates for building next-generation photodetectors (PDs). However, combining their excellent properties with satisfactory long-term robustness is still challenging, ultimately limiting the practical applications of HP-based PDs. Herein, a high vacuum deposition system is employed to fabricate flexible self-powered PDs with a ZnO/CsPbBr3/γ-CuI structure, which shows excellent stability and outstanding performance in weak light detection. Benefiting from the improved crystallinity and optimized device structure, a high detectivity of 8.1 × 1013 Jones and a rapid response speed (rise/decay time of 3.9/1.8 μs) are obtained in this self-powered device. Furthermore, the unencapsulated device exhibits intriguing environmental stability and mechanical flexibility. The photocurrent remains unchanged after 7000 s of continuous operation or 100 bending cycles. Furthermore, a 15 × 15 PD array is fabricated as an image sensor. A high contrast image of the target object can be obtained owing to the high sensitivity and uniformity of the self-powered PDs. These results demonstrate the feasibility and practicality of the ZnO/CsPbBr3/γ-CuI heterojunction for applications in weak light detection and image formation.

Topics & Concepts

Materials scienceOptoelectronicsPhotodetectorHeterojunctionPhotocurrentResponse timeRobustness (evolution)DetectorOpticsNanotechnologyComputer scienceChemistryBiochemistryPhysicsComputer graphics (images)GenePerovskite Materials and ApplicationsZnO doping and propertiesGa2O3 and related materials
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