Site-selective ligand defects open up a Zr-oxo cluster electron transfer pathway for CO <sub>2</sub> photoreduction
Yuhang Qi, Yiqiang He, Yuxin Liu, Zhe Zhang, Chunguang Li, Fanchao Meng, Shiyu Wang, Xiaobo Chen, Zhan Shi, Shouhua Feng
Abstract
-Zr pathways, effectively narrowing the band gap and suppressing photoinduced charge recombination. These findings are expected to provide alternative perspectives on selective defect engineering for the design and manufacture of high-performance MOF photo-catalysts for a variety of value-added engineering applications.
Topics & Concepts
Cluster (spacecraft)Electron transferLigand (biochemistry)Metal-organic frameworkAtomic unitsMaterials scienceElectronChemistryPhotochemistryNanotechnologyComputer scienceOrganic chemistryPhysicsAdsorptionReceptorQuantum mechanicsProgramming languageBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Photocatalysis TechniquesNanocluster Synthesis and Applications