Microwave-assisted synthesis of porous and hollow <i>α</i> -Fe <sub>2</sub> O <sub>3</sub> /LaFeO <sub>3</sub> nanostructures for acetone gas sensing as well as photocatalytic degradation of methylene blue
Dongming Zhang, Mingpeng Chen, Haiyuan Zou, Yumin Zhang, Jicu Hu, Huapeng Wang, Baoye Zi, Jin Zhang, Zhongqi Zhu, Lele Duan, Qingju Liu
Abstract
Abstract To address the urgent issues of hazardous gas detection and the prevention of environmental pollution, various functional materials for gas sensing and catalytic reduction have been studied. Specifically, the p-type perovskite LaFeO 3 has been studied widely because of its promising physicochemical properties. However, there remains several problems to develop a controllable synthesis of LaFeO 3 -based p-n heterojunctions. In this work, α -Fe 2 O 3 was further compounded with LaFeO 3 to form a porous and hollow α -Fe 2 O 3 /LaFeO 3 heterojunction to improve its gas-sensing performance and photocatalytic efficiency via a microwave-assisted hydrothermal method. While evaluated as sensors of acetone gas, the optimized sample exhibits excellent performance, including a high response (48.3), excellent selectivity, good reversibility, fast response, and recovery ability. Furthermore, it is an efficient catalyst for the degradation of methylene blue. This can be attributed to the enhancement effect of its larger specific surface area, fast diffusion, enhanced surface activities, and p-n heterojunction. Additionally, this work provides a rapid and rational synthesis strategy to produce metal oxides with both enhanced gas-sensing performance and improved photocatalytic properties.