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On the Temperature-Dependence of Deformation-Induced Martensite Formation in AISI 304L Type Steel

Gero Egels, Markus Bussmann, Santiago Benito, Sebastian Weber

2023Metallurgical and Materials Transactions A13 citationsDOIOpen Access PDF

Abstract

Abstract In this study, the deformation-induced α-martensite formation in AISI 304L steel was investigated in the temperature range between 75 °C and − 196 °C in the light of the temperature-dependence of hydrogen embrittlement phenomena. For this purpose, tensile tests with in-situ and ex-situ magnetic measurement of the α-martensite volume content as a function of plastic strain were carried out. In addition, a theoretical assessment of the temperature-dependence of the austenite stability was undertaken, evaluating chemical and non-chemical driving force contributions to the martensitic γ → α transformation as proposed by Ghosh and Olson. The experimental results clearly show an increase in the α-martensite volume content and a shifting of the phase transformation to lower strain levels upon reducing the temperature to − 75 °C. A further reduction of the temperature to − 196 °C revealed to have no significant impact on the α-martensite formation. The theoretical assessments indicate a similar temperature-dependence of the austenite stability as observed experimentally and suggest contributions of the thermal friction work at the fcc/bcc interface to be responsible for a constant austenite stability in low-temperature regimes. Additional investigations of deformed microstructures showed that element segregation effects on the local austenite stability are pronounced around room temperature, but become less relevant at low temperatures.

Topics & Concepts

Materials scienceAusteniteMartensiteMetallurgyAtmospheric temperature rangeDiffusionless transformationMicrostructureDeformation (meteorology)EmbrittlementComposite materialThermodynamicsPhysicsMicrostructure and Mechanical Properties of SteelsHydrogen embrittlement and corrosion behaviors in metalsHigh Temperature Alloys and Creep
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