Litcius/Paper detail

Cu<sub>2</sub>O/CuO Electrocatalyst for Electrochemical Reduction of Carbon Dioxide to Methanol

Animesh Roy, Harsharaj S. Jadhav, Jeong Gil Seo

2020Electroanalysis74 citationsDOI

Abstract

Abstract Herein, we report the controlled and direct fabrication of Cu 2 O/CuO thin film on the conductive nickel foam using electrodeposition route for the electrochemical reduction of carbon dioxide (CO 2 ) to methanol. The electrocatalytic reduction was performed in CO 2 saturated aqueous solution consisting of KHCO 3 , pyridine and HCl at room temperature. CO 2 reduction was carried out at a constant potential of −1.3 V for 120 min to study the electrochemical performance of the prepared electrocatalysts. Cu 2 O/CuO shows better electrocatalytic activity with highest current density of 46 mA/cm 2 . The prepared catalyst can be an efficient and selective electrode for the production of methanol.

Topics & Concepts

ElectrocatalystMethanolElectrochemistryElectrochemical reduction of carbon dioxideCatalysisAqueous solutionInorganic chemistryMaterials scienceCarbon dioxideElectrodeCarbon fibersNickelChemistryCarbon monoxideMetallurgyOrganic chemistryComposite materialPhysical chemistryComposite numberCO2 Reduction Techniques and CatalystsIonic liquids properties and applicationsAdvanced Thermoelectric Materials and Devices