Autocatalytic deoximation reactions driven by visible light
Hongjia Li, Xiaobi Jing, Yaocheng Shi, Lei Yu
Abstract
Photocatalytic deoximation reaction was found to be an autocatalytic process that occurs <italic>via</italic> free-radical mechanism. Understanding the mechanism may help chemical engineers to develop related techniques to avoid the decomposition of oximes.
Topics & Concepts
AutocatalysisPhotocatalysisReaction mechanismChemistryMechanism (biology)PhotochemistryAutocatalytic reactionPhotodissociationDecompositionChemical reactionCatalysisOrganic chemistryPhysicsQuantum mechanicsStatistical physicsRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods