Metal-free visible light-induced cross-dehydrogenative coupling of benzocyclic imines with water/P(O)H compounds: efficient access to functionalized benzazepines/ones
Zhi-Cheng Fu, Luping Feng, Yu Q, Xinhui Mu, Xuqing Zhong, Zhouyu Wang, Ting Wang, Jinni Deng, Jingfang Li, Ming‐Jun Chen
Abstract
A metal-free visible light-induced cross-dehydrogenative coupling of aldimines with nucleophiles in a one-pot fashion is first reported, which features high efficiency,the absence of external oxidants, and mild and redox-neutral reaction conditions.
Topics & Concepts
ChemistryAldimineBenzazepinesPhotochemistryNucleophileMetalCoupling reactionNucleophilic additionVisible spectrumCoupling (piping)Combinatorial chemistryStereochemistryOrganic chemistryCatalysisOptoelectronicsMechanical engineeringEngineeringPhysicsRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods