Stoichiometric couplings of methylarenes through visible-light-induced bromo radical formation from aryl halides
Qiaolin Wang, Zhaozhao Sun, Huawen Huang, Guojiang Mao, Guo‐Jun Deng
Abstract
The unique merger of photocatalysis, nickel catalysis and bromo radical-enhanced HAT proved to be the key to the success of stoichiometric couplings of methylarenes and aryl bromine.
Topics & Concepts
HalideStoichiometryArylChemistryVisible spectrumAryl radicalPhotochemistryInorganic chemistryMaterials scienceOrganic chemistryAlkylOptoelectronicsRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsSulfur-Based Synthesis Techniques