Synthetic approaches for accessing rare-earth analogues of UiO-66
P. Rafael Donnarumma, Sahara Frojmovic, Paola Marino, Hudson A. Bicalho, Hatem M. Titi, Ashlee J. Howarth
Abstract
Rare-earth (RE) analogues of UiO-66 with non-functionalised 1,4-benzenedicarboxylate linkers are synthesised for the first time, and a series of synthetic approaches is provided to troubleshoot the synthesis. RE-UiO-66 analogues are fully characterised, and demonstrate a high degree of crystallinity, high surface area and thermal stability, consistent with the UiO-66 archetype.
Topics & Concepts
Rare earthCombinatorial chemistrySeries (stratigraphy)Earth (classical element)ChemistryAstrobiologyGeologyMineralogyPhysicsPaleontologyMathematical physicsMetal-Organic Frameworks: Synthesis and ApplicationsRadioactive element chemistry and processingLanthanide and Transition Metal Complexes