Switching the magnetostructural coupling in MnCoGe-based magnetocaloric materials
Xuefei Miao, Yong Gong, L. Caron, Yurong You, Guizhou Xu, Denis Sheptyakov, Pascal Manuel, Fengjiao Qian, Yujing Zhang, Feng Xu, Niels van Dijk, E. Brück
Abstract
We performed neutron-diffraction experiments and density functional theory calculations to study the magnetostructural coupling in $\mathrm{MnCoGe}{\mathrm{B}}_{x}$ ($x=0$, 0.01, and 0.05) alloys. By varying the amount of boron addition, we are able to freely switch the magnetostructural coupling on and off in the MnCoGe alloys. It is found that the boron addition stabilizes the high-temperature hexagonal phase due to the reduced interatomic distances and the enhanced covalent bonding. The hexagonal-orthorhombic structural transition shifts to low temperatures with the boron addition and coincides with the paramagnetic-ferromagnetic (PM-FM) transition in the $\mathrm{MnCoGe}{\mathrm{B}}_{0.01}$ alloy. With a further increase in the boron addition, the structural and magnetic transitions are decoupled again. The hexagonal-orthorhombic structural transition is significantly suppressed in the $\mathrm{MnCoGe}{\mathrm{B}}_{0.05}$ alloy, although subtle distortions in the hexagonal structure are evidenced by a canted spin arrangement below 75 K. The MnCoGe and $\mathrm{MnCoGe}{\mathrm{B}}_{0.01}$ alloys show a collinear FM structure, having a much larger Mn moment than the $\mathrm{MnCoGe}{\mathrm{B}}_{0.05}$ alloy. The relatively small Mn moment in the $\mathrm{MnCoGe}{\mathrm{B}}_{0.05}$ alloy can be attributed to the shortened Mn-Mn distance and the enhanced overlap of the $3d$ orbitals between the neighboring Mn atoms. The uncovered relationship between the structural evolution and the sizable magnetic moment in the present work offers more insight into the magnetostructural coupling in the MnCoGe-based alloys.