Aqueous Persistent Noncovalent Ion-Pair Cooperative Coupling in a Ruthenium Cobaltabis(dicarbollide) System as a Highly Efficient Photoredox Oxidation Catalyst
Isabel Guerrero, Clara Viñas, Xavier Fontrodona, Isabel Romero, Francesç Teixidor
Abstract
, with the same concentrations and ratios of Ru/Co, proving the history relevance of the photocatalyst. Cooperative systems with this type of interaction have not been described and represent a step forward in getting cooperativity avoiding costly covalent bonding. A possible mechanism has been proposed.
Topics & Concepts
ChemistryRutheniumCatalysisAqueous solutionCovalent bondAcetonitrilePhotochemistryTurnover numberLigand (biochemistry)Non-covalent interactionsPhotoredox catalysisHydrogen bondOrganic chemistryMoleculePhotocatalysisBiochemistryReceptorBoron Compounds in ChemistryRadioactive element chemistry and processingAdvanced Photocatalysis Techniques