Regioselective Functionalization of the Mesoporous Metal–Organic Framework, NU-1000, with Photo-Active Tris-(2,2′-bipyridine)ruthenium(II)
Hisanori Nagatomi, Leighanne C. Gallington, Subhadip Goswami, Jiaxin Duan, Karena W. Chapman, Nobuhiro Yanai, Nobuo Kimizuka, Omar K. Farha, Joseph T. Hupp
Abstract
SALI. Crystallographic information regarding the siting of the ruthenium complex within the MOF pores is obtained by difference envelope density analysis. The ruthenium-functionalized MOF, termed Ru-NU-1000, shows excellent heterogeneous photocatalytic activity for an oxidative amine coupling reaction.
Topics & Concepts
RutheniumSurface modificationChemistryBipyridineMetal-organic frameworkCarboxylateLigand (biochemistry)ProtonationAmine gas treatingPolymer chemistryPhotochemistryCombinatorial chemistryCatalysisOrganic chemistryPhysical chemistryCrystal structureAdsorptionReceptorBiochemistryIonMetal-Organic Frameworks: Synthesis and ApplicationsPolyoxometalates: Synthesis and ApplicationsCovalent Organic Framework Applications