Photocatalytic CO<sub>2</sub> reduction to C<sub>2+</sub> products using a metal–organic framework composited with facet engineered Pd nanoparticles
Xiangyu Lu, Qiang Zhou, Xiaoyu Zhang, Ya Zhang, Feng Gong, Wei‐Yin Sun
Abstract
The ability of MIL-100(Fe) to photoreduce CO 2 to C 2 H 4 is enhanced by loading Pd NPs with {111} facets, which can facilitate migration and separation of photoelectrons and lower the energy barrier in the decisive step of the coupling reaction.
Topics & Concepts
PhotocatalysisFacet (psychology)Reduction (mathematics)Materials scienceMetal-organic frameworkNanoparticleMetalChemical engineeringNanotechnologyCatalysisChemistryMetallurgyOrganic chemistryEngineeringBig Five personality traitsGeometryAdsorptionPsychologySocial psychologyPersonalityMathematicsCO2 Reduction Techniques and CatalystsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications