Litcius/Paper detail

Carbon Fibers Enhance the Propagation of High Loading Nanothermites: In Situ Observation of Microscopic Combustion

Haiyang Wang, Dylan J. Kline, Miles C. Rehwoldt, Michael R. Zachariah

2021ACS Applied Materials & Interfaces41 citationsDOI

Abstract

A major challenge in formulating and manufacturing energetic materials lies in the balance between total energy density, energy release rate, and mechanical integrity. In this work, carbon fibers are embedded into ∼90 wt % loading Al/CuO nanothermite sticks through a simple extrusion direct writing technique. With only ∼2.5 wt % carbon fiber addition, the burn rate and heat flux were promoted >2×. In situ microscopic observation of combustion shows that the carbon fiber intercept ejected hot agglomerates near the burning surface and enhanced heat feedback to the unreacted material. This study outlines how these approaches may enhance the propagation and reduce the two-phase flow losses.

Topics & Concepts

Materials scienceAgglomerateCombustionComposite materialFiberExtrusionCarbon fibersIn situWork (physics)Volumetric flow rateChemical engineeringMechanical engineeringMechanicsEngineeringPhysicsOrganic chemistryChemistryComposite numberMeteorologyEnergetic Materials and CombustionRocket and propulsion systems researchThermal and Kinetic Analysis