Polymerization of epoxide monomers promoted by <i>t</i>BuP<sub>4</sub> phosphazene base: a comparative study of kinetic behavior
Valentin Puchelle, Haiqin Du, Nicolas Illy, Philippe Guégan
Abstract
This contribution fills the need for quantitative mechanistic and kinetic information for epoxide polymerizations catalyzed by <italic>t</italic>BuP<sub>4</sub> phosphazene base.
Topics & Concepts
PhosphazeneEpoxideChemistryPolymerizationBase (topology)Kinetic energyMonomerPolymer chemistryOrganic chemistryCatalysisPolymerQuantum mechanicsMathematical analysisMathematicsPhysicsCarbon dioxide utilization in catalysisbiodegradable polymer synthesis and propertiesSynthetic Organic Chemistry Methods