Photoreductive chlorine elimination from a Ni( <scp>iii</scp> )Cl <sub>2</sub> complex supported by a tetradentate pyridinophane ligand
Hanah Na, Michael B. Watson, Fengzhi Tang, Nigam P. Rath, Liviu M. Mirica
Abstract
We report a facile photoreductive chlorine elimination reaction from a stable Ni( <sc>iii</sc> ) dichloride complex supported by a tetradentate pyridinophane N-donor ligand.
Topics & Concepts
ChemistryLigand (biochemistry)ChlorineStereochemistryReceptorBiochemistryOrganic chemistryCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsPolyoxometalates: Synthesis and Applications