Copper-catalyzed synthesis of cyclopropyl bis(boronates) from aryl olefins and carbon monoxide
Hui‐Qing Geng, Wenbo Li, Yanying Zhao, Xiao‐Feng Wu
Abstract
A copper-catalyzed carbonylation process has been developed for the synthesis of diborylated cyclopropanes from both stable internal and terminal aryl olefins in moderate to good yields.
Topics & Concepts
ChemistryArylCarbon monoxideCarbonylationCatalysisCopperOrganic chemistryCombinatorial chemistryMedicinal chemistryAlkylCyclopropane Reaction MechanismsCatalytic C–H Functionalization MethodsOrganoboron and organosilicon chemistry