Rational design of a phenothiazine-based donor–acceptor covalent organic framework for enhanced photocatalytic oxidative coupling of amines and cyclization of thioamides
Yang Liu, Xinyue Jiang, Likun Chen, Yan Cui, Qiuyan Li, Xinsheng Zhao, Xiguang Han, Yongchao Zheng, Xiaojun Wang
Abstract
A PTZ-based D–A COF with low exciton binding energy and high charge separation efficiency exhibited an enhanced photocatalytic performance in oxidative amine coupling and cyclization of thioamide reactions.
Topics & Concepts
Oxidative coupling of methanePhotocatalysisThioamideChemistryPhenothiazineAmine gas treatingCovalent bondAcceptorPhotochemistryOxidative phosphorylationCoupling (piping)Combinatorial chemistryMaterials scienceOrganic chemistryCatalysisPharmacologyMedicinePhysicsBiochemistryMetallurgyCondensed matter physicsCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications