A Microporous Hydrogen Bonded Organic Framework for Highly Selective Separation of Carbon Dioxide over Acetylene
Yunbin Li, Xue Wang, Hao Zhang, Lei He, Jiali Huang, Wuji Wei, Zhen Yuan, Zhile Xiong, Huadan Chen, Shengchang Xiang, Banglin Chen, Zhangjing Zhang
Abstract
Abstract The separation of acetylene (C 2 H 2 ) from carbon dioxide (CO 2 ) is a very important but challenging task due to their similar molecular dimensions and physical properties. In terms of porous adsorbents for this separation, the CO 2 ‐selective porous materials are superior to the C 2 H 2 ‐selective ones because of the cost‐ and energy‐efficiency but have been rarely achieved. Herein we report our unexpected discovery of the first hydrogen bonded organic framework (HOF) constructed from a simple organic linker 2,4,6‐tri(1 H ‐pyrazol‐4‐yl)pyridine (PYTPZ) (termed as HOF‐FJU‐88) as the highly CO 2 ‐selective porous material. HOF‐FJU‐88 is a two‐dimensional HOFs with a pore pocket of about 7.6 Å. The activated HOF‐FJU‐88 takes up a high amount of CO 2 (59.6 cm 3 g −1 ) at ambient conditions with the record IAST selectivity of 1894. Its high performance for the CO 2 /C 2 H 2 separation has been further confirmed through breakthrough experiments, in situ diffuse reflectance infrared spectroscopy and molecular simulations.