Litcius/Paper detail

A mechanism theory of dissolution profile of oxide particles in oxide melt

Changji Xuan, Wangzhong Mu

2020Journal of the American Ceramic Society22 citationsDOIOpen Access PDF

Abstract

Abstract The shape origin and variation of oxide dissolution profile in the oxide melt is for the first time explained with a mechanism of diffusion‐distance‐controlled dissolution (DDD). A novel analytical model is derived to present this theory. The profile shape is governed by the diffusion distance of the dissolved components in the oxide melt. The viscosity gradient at the boundary of the diffusion region provides the driving force for the profile variation. Both temperature and initial viscosity of oxide melt are the key factors determining the oxide dissolution kinetics. This theory can be applied to describe diffusion‐limited particle dissolution in a general system.

Topics & Concepts

DissolutionOxideDiffusionViscosityMaterials scienceThermodynamicsKineticsChemical physicsChemistryChemical engineeringPhysical chemistryMetallurgyComposite materialPhysicsClassical mechanicsEngineeringSolidification and crystal growth phenomenaMetallurgical Processes and ThermodynamicsAdvanced ceramic materials synthesis