Litcius/Paper detail

Reaction Mechanism of Aldehyde Groups during Coal Self-Heating

Xuyao Qi, Yawen Li, Liangzhou Chen, Jie Tang, Haihui Xin, Zhongqiu Liang

2020ACS Omega30 citationsDOIOpen Access PDF

Abstract

generation during coal spontaneous combustion. The thermodynamic parameters of the elementary reactions were further analyzed and confirmed by quantum chemistry methods. The results are helpful for further understanding the pathways of CO generation in the initial stage of coal spontaneous combustion, which provides theoretical support for prediction of coal spontaneous combustion.

Topics & Concepts

AldehydeSpontaneous combustionChemistryElementary reactionReaction mechanismRadicalCombustionChemical reactionPhotochemistryComputational chemistryOrganic chemistryCatalysisKineticsPhysicsQuantum mechanicsCoal Properties and UtilizationCombustion and Detonation ProcessesCombustion and flame dynamics