Selective Synthesis of <i>Z</i>-Silyl Enol Ethers via Ni-Catalyzed Remote Functionalization of Ketones
Sinem Guven, Gourab Kundu, Andrea Weßels, Jas S. Ward, Kari Rissanen, Franziska Schoenebeck
Abstract
enolate as the key selectivity-controlling intermediate.
Topics & Concepts
ChemistrySilylationCatalysisSilyl enol etherEnolSurface modificationSelectivityBromideSilyl etherOlefin fiberAlkylEtherCombinatorial chemistryOrganic chemistryPhysical chemistryCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization MethodsOrganoboron and organosilicon chemistry