Triazine-cored donor–acceptor covalent organic framework promotes highly efficient photocatalytic synthesis of H<sub>2</sub>O<sub>2</sub>
Lihua Li, Xin Yao, Weizhi Ou, Jing Chai, Ru Ma, Chenglong Ran, Anzhi Ma, Xiaojun Shi, Pifeng Wei, Hong Dong, Hongpeng Zhou, Wen-Bing Yang, Hai‐Yu Hu, Jianfeng Wu, Hui Peng, Guofu Ma
Abstract
A D–A COF (TPB–TPT-COF) with triazine groups enabled photocatalytic H 2 O 2 production at 6740 μmol g −1 h −1 without sacrificial agents. DFT and experiments show its D–A structure boosts carrier separation and transport for enhanced performance.
Topics & Concepts
Covalent bondTriazinePhotocatalysisAcceptorChemistryPhotochemistryCombinatorial chemistryMaterials sciencePolymer chemistryOrganic chemistryCatalysisPhysicsCondensed matter physicsAdvanced Photocatalysis TechniquesCovalent Organic Framework ApplicationsCaching and Content Delivery