Current Advances in Meerwein-type Radical Alkene Functionalizations

Abstract

Abstract Alkene functionalizations via Meerwein arylations are becoming increasingly attractive, especially since a variety of mild and sustainable methods for aryl radical generation are available today. This entails a broad spectrum of substrates and radical scavengers, as well as convenient synthetic routes to relevant precursors for further transformations. The present review focuses on recent advances in Meerwein-type alkene functionalizations and gives insights into the key mechanistic details of the respective reactions. 1 Introduction 2 Hydroarylation and Carboarylation 3 Carboamination, Carbooxygenation, and Carbothiolation 4 Carbohalogenation 5 Conclusion and Outlook

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