Ag<sup>1+</sup> incorporation <i>via</i> a Zr<sup>4+</sup>-anchored metalloligand: fine-tuning catalytic Ag sites in Zr/Ag bimetallic clusters for enhanced eCO<sub>2</sub>RR-to-CO activity
Liangjun Li, Wen-Lei Mu, Yi-Qi Tian, Wei‐Dong Yu, Lan-Yan Li, Jun Yan, Chao Liu
Abstract
We employed three structurally closely-related Zr/Ag bimetallic nanoclusters as model catalysts to conduct a precise comparison of the catalytic activity of three distinct Ag sites in CO 2 electroreduction at the molecular level.
Topics & Concepts
Bimetallic stripNanoclustersCatalysisChemistryCrystallographyPhysical chemistryMaterials scienceNanotechnologyOrganic chemistryNanocluster Synthesis and ApplicationsCO2 Reduction Techniques and CatalystsCarbon dioxide utilization in catalysis