Electrochemical nickel-catalysed defluoroalkylation of<i>gem</i>-difluoroalkenes with alkyl halides
Liu Yin, Pengfei Li, Jun Tan, Guangsheng Kou, Dengke Ma, Youai Qiu
Abstract
Herein, a direct and efficient electrochemical method for the synthesis of monofluoroalkene products was promoted using gem -difluoroalkenes and unactivated alkyl halides as starting materials with a nickel catalyst.
Topics & Concepts
HalideAlkylNickelElectrochemistryChemistryCatalysisCombinatorial chemistryOrganic chemistryElectrodePhysical chemistryFluorine in Organic ChemistryInorganic Fluorides and Related CompoundsRadical Photochemical Reactions