Selective C(sp<sup>3</sup>)–H activation of simple alkanes: visible light-induced metal-free synthesis of phenanthridines with H<sub>2</sub>O<sub>2</sub> as a sustainable oxidant
Yongqiang Zhang, Yunhe Jin, Lifang Wang, Qingqing Zhang, Changgong Meng, Chunying Duan
Abstract
A visible light-induced metal-free C(sp 3 )–H phenanthridinylation of simple alkanes with isonitrile is developed with H 2 O 2 as a terminal sustainable oxidant.
Topics & Concepts
ChemistryVisible spectrumMetalSimple (philosophy)PhotochemistryOrganic chemistryMaterials scienceOptoelectronicsEpistemologyPhilosophyCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques