A concerted evolution of supramolecular interactions in a {cation; metal complex; π-acid; solvent} anion-π system
Emilia Kuźniak, James Hooper, Monika Srebro‐Hooper, Jędrzej Kobylarczyk, Magdalena Dziurka, Bogdan Musielak, Dawid Pinkowicz, Jésus Raya, Sylvie Ferlay, Robert Podgajny
Abstract
Comprehensive studies on a concerted evolution of supramolecular interactions with multicomponent synthon reproduction provide a new tool to describe the trapping of flat [M(L)<sub>4</sub>]<sup>2−</sup> complexes within π-acidic cavities.
Topics & Concepts
SynthonSupramolecular chemistryChemistrySolventMetalIonComputational chemistryInorganic chemistryCrystallographyStereochemistryOrganic chemistryCrystal structureCrystallography and molecular interactionsMolecular spectroscopy and chiralityCrystal structures of chemical compounds