Donor engineering of diphenylamine-substituted tris(2,4,6-trichlorophenyl)methyl radicals for controlling the intramolecular charge transfer and near-infrared photothermal conversion
Chuan Yan, Jing Fang, Jiangyu Zhu, Weinan Chen, Min Wang, Kai Chi, Xuefeng Lu, Gang Zhou, Yunqi Liu
Abstract
Donor engineering of diphenylamine-substituted tris(2,4,6-trichlorophenyl)methyl (TTM) radicals triggers the switching of the TTM-based radicals from the photoluminescent to NIR photothermal mode.
Topics & Concepts
DiphenylamineRadicalPhotochemistryIntramolecular forceMaterials scienceTrisInfraredMolecular engineeringPhotothermal therapyPhotoluminescenceChemistryOrganic chemistryOptoelectronicsNanotechnologyOpticsPhysicsBiochemistryMetallurgyPerovskite Materials and ApplicationsLuminescence and Fluorescent MaterialsOrganic and Molecular Conductors Research