Interfacial Engineering of Mo<sub>x</sub>S<sub>y</sub> via Boron‐Doping for Electrochemical N<sub>2</sub>‐to‐NH<sub>3</sub> Conversion
Merfat M. Alsabban, Karthik Peramaiah, Alessandro Genovese, Rafia Ahmad, Luis Miguel Azofra, Vinoth Ramalingam, Mohamed Nejib Hedhili, Nimer Wehbe, Luigi Cavallo, Kuo‐Wei Huang
Abstract
Abstract The electrocatalytic synthesis of ammonia (NH 3 ) through the nitrogen reduction reaction (NRR) under ambient temperature and pressure is emerging as an alternative approach to the conventional Haber–Bosch process. However, it remains a significant challenge due to poor kinetics, low nitrogen (N 2 ) solubility in aqueous electrolytes, and the competing hydrogen evolution reaction (HER), which can significantly impact NH 3 production rates and Faradaic efficiency (FE). Herein, a rationally designed boron‐doped molybdenum sulfide (B‐Mo‐Mo x S y ) electrocatalyst is reported that effectively enhances N 2 reduction to NH 3 with an onset potential of −0.15 V versus RHE, achieving a FE of 78% and an NH 3 yield of 5.83 µg h⁻¹ cm⁻ 2 in a 0.05 m H 2 SO 4 (aq). Theoretical studies suggest that the effectiveness of NRR originates from electron density redistribution due to boron (B) doping, which provides an ideal pathway for nitrogenous species to bind with electron‐deficient B sites. This work demonstrates a significant exploration, showing that Mo‐based electrocatalysts are capable of facilitating artificial N 2 fixation.