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A Chemical Approach to Introduce 2,6-Diaminopurine and 2-Aminoadenine Conjugates into Oligonucleotides without Need for Protecting Groups

Mimouna Madaoui, Dhrubajyoti Datta, Kelly Wassarman, Ivan Zlatev, Martin Egli, Bruce S. Ross, Muthiah Manoharan

2022Organic Letters13 citationsDOIOpen Access PDF

Abstract

feasible at the 2-position.

Topics & Concepts

ChemistryOligonucleotideNucleotideConjugateCombinatorial chemistryProtecting groupNucleophilic substitutionNucleic acidStereochemistryLeaving groupAdenosineNucleophileFluorineOrganic chemistryBiochemistryCatalysisMathematical analysisDNAGeneMathematicsAlkylDNA and Nucleic Acid ChemistryClick Chemistry and ApplicationsAdvanced biosensing and bioanalysis techniques