Ligand effects on structural, protophilic and reductive features of stannylated dinuclear iron dithiolato complexes
Hassan Abul‐Futouh, Laith R. Almazahreh, Sara J. Abaalkhail, Helmar Görls, Sven T. Stripp, Wolfgang Weigand
Abstract
The synthesis and characterization of Fe <sub>2</sub> (CO) <sub>5</sub> (L){μ-(SCH <sub>2</sub> ) <sub>2</sub> SnMe <sub>2</sub> } (L = PPh <sub>3</sub> ( <bold>2</bold> ) and P(OMe) <sub>3</sub> ( <bold>3</bold> )) derived from the parent hexacarbonyl complex Fe <sub>2</sub> (CO) <sub>6</sub> {μ-(SCH <sub>2</sub> ) <sub>2</sub> }SnMe <sub>2</sub> ( <bold>1</bold> ) are reported.
Topics & Concepts
ChemistryCrystallographyLigand (biochemistry)X-ray crystallographyStereochemistryPhysicsDiffractionBiochemistryOpticsReceptorMetalloenzymes and iron-sulfur proteinsMetal complexes synthesis and propertiesMagnetism in coordination complexes